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5. Conclusion
The relationship between nonylphenol (NP) isomer structure and its biodegradability within the biological wastewater treatment process of sequencing batch reactor (SBR) was investigated in this study. The GC MS method was used for detecting the NP isomers existing in the SBR influent, activated sludge and effluent. The results indicated that fifteen NP isomers were detected in the SBR influent, with significant biodegradability variations among these isomers. The NP isomers associated with retention time of 10.553 min, 10.646 min, 10.774 min, and 10.906 min in the GC– MS analysis showed higher biodegradability. The isomers with retention time of 10.475 min, 10.800 min, and 10.857 min illustrated
lower biodegradability, and these three NP isomers accounted for the major part of residual NP in the SBR effluent and the sludge. An increasing amount of these three NP isomers in
sludge was also observed with an increasing running cycles of SBR. Through analyzing the mass spectrograms, the chemical structures of four NP isomers in the wastewater were deduced. The isomers with retention time of 10.475 min, 10.800 min, 10.857 min, and 10.774 min were identified as 4-(1,3 dimethyl- 1-propyl-butyl)phenol, 4-(1-ethyl-1,3-dimethyl-pentyl)phenol, 4- (1-ethyl-1,3,3-trimethyl butyl)phenol, and 4-(1,1,3-trimethylhexyl) phenol, respectively. The correlation between the biodegradability of NP isomer and its structure was then examined through the calculation of the molecular connectivity index (MCI) and the biodegradation rate of the four NP isomers in the SBR. A higher correlation (with correlation coefficients of 0.9421 and 0.9085) was
observed between the biodegradation rates and the MCI of 2vv and 4vv pc, where 2vv indicated the number of the branch chain and its carbon atom in the nonyl of NP, and 4vv represented the
information of the nonyl length of NP.
お礼
この問題のタイトルが [The heart]なので心臓に限った問題なのですがおそらく解答は全体的な生物学的な所見を踏まえて述べるものだと思うのですが。。。 やはり心室と心房のシステムにより血液の循環系がそもそも違うということが答えでいいのでしょうか? でもそれがそのまま英文で真上に書いてあるのでどうもしっくりこなかったのですが御教授くださったおかげで安心しました。